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Analysis Description EPA method or other reference
Analyte
Units
MDL
Typical Range
Anions Anions via ion chromatography w/ suppressed conductivity. Anions EPA #300.1
Cl-
mg Cl/L 
0.02
0 – 15
NO3
mg N/L 
0.002
0 – 3
SO4
mg S/L
0.04
0 – 8
Cations Cations via ion chromatography
and conductivity
Proposed EPA method
Na
mg Na/L
0.1
0 – 15
K
mg K/L 
0.05
0 – 7
Mg
mg Mg/L 
0.1
0 – 7
Ca
mg Ca/L
0.1
0 – 10
DOC High Temperature Catalytic
Oxidation (HTCO)
EPA 415.1
DOC
mg C/L
0.05
0 - 20
TDN HTCO with chemiluminescent
N detection
Merriam et al, 1996
TDN
mg N/L
0.09
0 - 10
DOC and TDN HTCO with chemiluminescent
N detection
EPA 415.1 and
Merriam et al, 1996
DOC and
TDN

mg C/L
mg N/L

0.05
0.09 
0 - 20
0 - 10
Nitrate/Nitrite colorimetric NO3/NO2 Automated Cd-Cu reduction EPA 353.2  
NO3/NO2
mg N/L
0.005

0 - 10

Ammonium colorimetric NH4 Automated Phenate EPA 350.1
NH4
ug N/L
5
0 - 200
Soluble reactive Phosphorous colorimetric PO4 Automated Ascorbic acid EPA 365  
PO4
ug N/L
5
0 - 200
Silica colorimetric Automated Ascorbic/ANSA   EPA 370.1
SiO2
mg SiO2/L
0.01
0 - 40
CHN on solid samples Automated Carbon, Nelson et al, 1996; Nitrogen, Bremner 1996
C, H, N
% and/or ug
50 - 2000 ug C
10 - 500 ug N
Analysis Description EPA method or other reference
Analyte
Units
MDL
Typical Range